Enhanced Electrochemical Performance of Li4Ti5O12 by Niobium Doping for Pseudocapacitive Applications
نویسندگان
چکیده
Niobium-doped nanocrystalline Li4Ti5O12 (LTO) is synthesized by the solid-state reaction method, and influence of dopant concentration (x = 2–10 mol%) on microstructural electrochemical properties studied. The X-ray diffraction Raman patterns assessed cubic spinel structure Li4Ti5−xNbxO12 phase in all samples. Marginal changes lattice parameters, unit cell volume dislocation density LTO are observed with Nb substitution. higher ionic radius induces a expansion, which may be favorable for more ion intercalation/deintercalation. SEM TEM images display uniformly distributed nano-sized cubical particles. represented (hkl) orientations SAED pattern d-spacing (0.46 nm) between bright fringes confirm well-crystallized phase. EDS elemental mapping results demonstrate that elements doped proper stoichiometric ratio. optimized 8%Nb-doped electrode exhibits pseudocapacitive behavior delivers high specific capacitance 497 F g−1 at current 1 A 92.3% retention even after 5000 cycles.
منابع مشابه
Stabilization of Oxygen-deficient Structure for Conducting Li4Ti5O12-δ by Molybdenum Doping in a Reducing Atmosphere
Li4Ti5O12 (LTO) is recognized as being one of the most promising anode materials for high power Li ion batteries; however, its insulating nature is a major drawback. In recent years, a simple thermal treatment carried out in a reducing atmosphere has been shown to generate oxygen vacancies (VO) for increasing the electronic conductivity of this material. Such structural defects, however, lead t...
متن کاملNiobium Alloyed High Strength Steels for Automotive Applications
Modern vehicle bodies make intensive use of high strength steel grades to meet the contradicting demand of lighter weight and simultaneously better mechanical performance. For many steel grades microalloying by niobium is the key to achieve their characteristic property profile. In HSLA steels niobium enhances the strength primarily by grain refinement. In interstitial free high strength steels...
متن کاملStructural and electrochemical properties of Gd-doped Li4Ti5O12 as anode material with improved rate capability for lithium-ion batteries
Study of Gd-doping level on the electrochemical performance of Li4Ti5O12. Greatly enhanced rate capability and retention of Gd-doped Li4Ti5O12 revealed. Analysis designed to determine the position and occupancy of Gd in Li4Ti5O12. Computation describes the fundamental mechanism of performance
متن کاملA Facile Surface Reconstruction Mechanism toward Better Electrochemical Performance of Li4Ti5O12 in Lithium‐Ion Battery
Through a facile sodium sulfide (Na2S)-assisted hydrothermal treatment, clean and nondefective surfaces are constructed on micrometer-sized Li4Ti5O12 particles. The remarkable improvement of surface quality shows a higher first cycle Coulombic efficiency (≈95%), a significantly enhanced cycling performance, and a better rate capability in electrochemical measurements. A combined study of Raman ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Micro
سال: 2021
ISSN: ['2673-8023']
DOI: https://doi.org/10.3390/micro1010004