Enhanced Electrochemical Performance of Li4Ti5O12 by Niobium Doping for Pseudocapacitive Applications

نویسندگان

چکیده

Niobium-doped nanocrystalline Li4Ti5O12 (LTO) is synthesized by the solid-state reaction method, and influence of dopant concentration (x = 2–10 mol%) on microstructural electrochemical properties studied. The X-ray diffraction Raman patterns assessed cubic spinel structure Li4Ti5−xNbxO12 phase in all samples. Marginal changes lattice parameters, unit cell volume dislocation density LTO are observed with Nb substitution. higher ionic radius induces a expansion, which may be favorable for more ion intercalation/deintercalation. SEM TEM images display uniformly distributed nano-sized cubical particles. represented (hkl) orientations SAED pattern d-spacing (0.46 nm) between bright fringes confirm well-crystallized phase. EDS elemental mapping results demonstrate that elements doped proper stoichiometric ratio. optimized 8%Nb-doped electrode exhibits pseudocapacitive behavior delivers high specific capacitance 497 F g−1 at current 1 A 92.3% retention even after 5000 cycles.

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ژورنال

عنوان ژورنال: Micro

سال: 2021

ISSN: ['2673-8023']

DOI: https://doi.org/10.3390/micro1010004